"Very long-range isotope shifts in the proton NMR spectra of deuteriate" by Craig J. Medforth, Fuu Yau Shiau et al.

Faculty Publications

Title

Very long-range isotope shifts in the proton NMR spectra of deuteriated haemins

Authors

Craig J. Medforth, University of California, Davis
Fuu Yau Shiau, University of California, Davis
Gerd N. La Mar, University of California, Davis
Kevin M. Smith, University of California, Davis

Document Type

Article

Publication Date

12-1-1991

Abstract

Very long-range isotope shifts have been observed in the 500 MHz proton NMR spectra of several deuteriated haemins; these shifts are consistent with a redistribution of delocalised π spin density upon fractional resolution, owing to deuteriation, of the ground state orbital degeneracy of the low-spin iron(III) ion.

Publication Source (Journal or Book title)

Journal of the Chemical Society, Chemical Communications

First Page

590

Last Page

592

Recommended Citation

Medforth, C., Shiau, F., La Mar, G., & Smith, K. (1991). Very long-range isotope shifts in the proton NMR spectra of deuteriated haemins. Journal of the Chemical Society, Chemical Communications (8), 590-592. https://doi.org/10.1039/C39910000590

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