Title
Construction of Inverse Metal-Zeolite Interfaces via Area-Selective Atomic Layer Deposition
Document Type
Article
Publication Date
11-3-2021
Abstract
The spatial confinement at metal-zeolite interfaces offers a powerful knob to steer the selectivity of chemical reactions on metal catalysts. However, encapsulating metal catalysts into small-pore zeolites remains a challenging task. Here, we demonstrate an inverse design of metal-zeolite interfaces, "" constructed by area-selective atomic layer deposition. This inverse design bypasses the intrinsic synthetic issues associated with metal encapsulation, offering a potential solution for the fabrication of task-specific metal-zeolite interfaces for desired catalytic applications. Infrared spectroscopy and several probe reactions confirmed the spatial confinement effects at the inverse metal-zeolite interfaces.
Publication Source (Journal or Book title)
ACS applied materials & interfaces
First Page
51759
Last Page
51766
Recommended Citation
Zhai, P., Zhang, L., Cullen, D. A., Aireddy, D. R., & Ding, K. (2021). Construction of Inverse Metal-Zeolite Interfaces via Area-Selective Atomic Layer Deposition. ACS applied materials & interfaces, 13 (43), 51759-51766. https://doi.org/10.1021/acsami.1c15569