(4,4′-Dimethyl-2,2′-bipyridine-k2 N,N′)bis-[2-(2-pyrid-yl)phenyl-k2 N,C 1]iridium(III) hexa-fluoridophosphate
Document Type
Article
Publication Date
11-9-2007
Abstract
The title compound, [Ir(C11H8N)2(C12H12N2)]PF6, an iridium complex with two cyclo-metallated 2-phenyl-pyridine fragments and one 4,4′-dimethyl-2, 2′-bipyridine unit, presents a distorted octa-hedral coordination geometry around the Ir atom. Charge balance is achieved through a hexa-fluoridophosphate anion. The coordination geometry of the two 2-phenylpyridine ligands around the IrIII centre retains the cis-C - C and trans-N - N chelate dispositions. © International Union of Crystallography 2007.
Publication Source (Journal or Book title)
Acta Crystallographica Section E: Structure Reports Online
Recommended Citation
Han, L., Li, B., & Ying, J. (2007). (4,4′-Dimethyl-2,2′-bipyridine-k2 N,N′)bis-[2-(2-pyrid-yl)phenyl-k2 N,C 1]iridium(III) hexa-fluoridophosphate. Acta Crystallographica Section E: Structure Reports Online, 63 (12) https://doi.org/10.1107/S1600536807059314