Copolymerization of schiff bases with tetracyanoethylene

Document Type

Article

Publication Date

1-1-1991

Abstract

The copolymerization of four Schiff bases (substituted benzylidine anilines) with tetracyanoethylene has been investigated. The reaction takes place in the absence of an initiator through a zwitterionic mechanism, leading to copolymers with an almost alternating structure. When dimethylformamide was used as solvent, a concur-rent radical homopolymerization of tetracyanoethylene with the formation of an azoporphyrin structure occurs. © 1991, Taylor & Francis Group, LLC. All rights reserved.

Publication Source (Journal or Book title)

Journal of Macromolecular Science: Part A - Chemistry

First Page

601

Last Page

612

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