Grain-boundary grooving by surface diffusion with asymmetric and strongly anisotropic surface energies
Document Type
Article
Publication Date
1-15-2006
Abstract
Grain-boundary migration controls grain growth, which is important in material processing and synthesis. When a vertical grain boundary ends at a horizontal free surface, a groove forms at the tip to reduce the combined grain-boundary and surface energies. The groove affects the migration of the grain boundary, and its effect must be understood. This work studies grain-boundary grooving by capillarity-driven surface diffusion with asymmetric and strongly anisotropic surface energies. The surface energies are described by the delta-function facet model that holds for temperatures above the roughening temperature of the bicrystal. Since the asymmetric anisotropy does not introduce a length scale, the asymmetric groove still grows with time t as t14. Thus, the nonlinear partial differential equation that governs grooving is reduced by a self-similar transformation to an ordinary differential equation, which is then solved numerically by shooting methods. We vary systematically the crystallographic orientations of the bicrystal and the normalized grain-boundary energy. We find that the self-similar groove profile is faceted and asymmetric for most bicrystals. However, a few asymmetric bicrystals can also yield smooth and symmetric grooves. Some bicrystals may even form ridges instead of grooves. We also find that the asymmetric surface energies tilt the grain-boundary tip sideways, which induces the grain boundary to migrate. We show that anisotropic groove profiles measured in SrTiO3 and Ni can be well fitted by our model. © 2006 American Institute of Physics.
Publication Source (Journal or Book title)
Journal of Applied Physics
Recommended Citation
Min, D., & Wong, H. (2006). Grain-boundary grooving by surface diffusion with asymmetric and strongly anisotropic surface energies. Journal of Applied Physics, 99 (2) https://doi.org/10.1063/1.2159082
