Title
Multiple H 2 occupancy of cages of clathrate hydrate under mild conditions
Document Type
Article
Publication Date
6-6-2012
Abstract
Experiments were carried out by reacting H 2 gas with N 2 hydrate at a temperature of 243 K and a pressure of 15 MPa. The characterizations of the reaction products indicated that multiple H 2 molecules can be loaded into both large and small cages of structure II clathrate hydrates. The realization of multiple H 2 occupancy of hydrate cages under moderate conditions not only brings new insights into hydrogen clathrates but also refreshes the perspective of clathrate hydrates as hydrogen storage media. © 2012 American Chemical Society.
Publication Source (Journal or Book title)
Journal of the American Chemical Society
First Page
9160
Last Page
9162
Recommended Citation
Lu, H., Wang, J., Liu, C., Ratcliffe, C., Becker, U., Kumar, R., & Ripmeester, J. (2012). Multiple H 2 occupancy of cages of clathrate hydrate under mild conditions. Journal of the American Chemical Society, 134 (22), 9160-9162. https://doi.org/10.1021/ja303222u