Title
Synthesis and characterization of a new binucleating tetraphosphine ligand based on 1,2-phenylene chelates and the structures of dinickel tetrachloride complexes of the ligand
Document Type
Article
Publication Date
10-6-2014
Abstract
A new binucleating tetraphosphine ligand, rac- and meso-(Et2P-1,2-C6H4)P(Ph)CH2(Ph)P(1,2-C6H4PEt2) (et,ph-P4-Ph), has been synthesized. Separation and purification of the ligand diastereomers have been accomplished via column chromatography. Ni2Cl4(et,ph-P4-Ph) complexes of both diastereomers have been prepared in high yield and crystallographically characterized.
Publication Source (Journal or Book title)
Inorganic chemistry
First Page
10036
Last Page
8
Recommended Citation
Schreiter, W. J., Monteil, A. R., Kalachnikova, E., Peterson, M. A., Moulis, M. D., Gasery, C. D., McCandless, G. T., Fronczek, F. R., & Stanley, G. G. (2014). Synthesis and characterization of a new binucleating tetraphosphine ligand based on 1,2-phenylene chelates and the structures of dinickel tetrachloride complexes of the ligand. Inorganic chemistry, 53 (19), 10036-8. https://doi.org/10.1021/ic5019345