Title
Structural complexity meets transport and magnetic anisotropy in single crystalline Ln30Ru4Sn31 (Ln = Gd, Dy)
Document Type
Article
Publication Date
2-20-2013
Abstract
We present the structure of Ln(30)Ru(4+x)Sn(31-y) (Ln = Gd, Dy) and the anisotropic resistivity, magnetization, thermopower, and thermal conductivity of single crystal Ln(30)Ru(4+x)Sn(31-y) (Ln = Gd, Tb). Gd(30)Ru(4.92)Sn(30.54) crystallizes in a new structure-type with space group Pnnm and dimensions of a = 11.784(1) Å, b = 24.717(1) Å, and c = 11.651(2) Å, and V = 3394(1) Å(3). Magnetic anisotropy and highly anisotropic electrical transport behavior were observed in the single crystals of Gd(30)Ru(4.92)Sn(30.54) and Tb(30)Ru(6)Sn(29.5). Additionally, the lattice thermal conductivity of Tb(30)Ru(6)Sn(29.5) is quite low, and a comparison is made to other Sn-containing compounds.
Publication Source (Journal or Book title)
Journal of the American Chemical Society
First Page
2748
Last Page
58
Recommended Citation
Schmitt, D. C., Haldolaarachchige, N., Prestigiacomo, J., Karki, A., Young, D. P., Stadler, S., Jin, R., & Chan, J. Y. (2013). Structural complexity meets transport and magnetic anisotropy in single crystalline Ln30Ru4Sn31 (Ln = Gd, Dy). Journal of the American Chemical Society, 135 (7), 2748-58. https://doi.org/10.1021/ja311779t
