Title
Probing the lower limit of lattice thermal conductivity in an ordered extended solid: Gd117Co56Sn112, a phonon glass-electron crystal system
Document Type
Article
Publication Date
4-4-2012
Abstract
The discovery of novel materials with low thermal conductivity is paramount to improving the efficiency of thermoelectric devices. As lattice thermal conductivity is inversely linked to unit cell complexity, we set out to synthesize a highly complex crystalline material with glasslike thermal conductivity. Here we present the structure, transport properties, heat capacity, and magnetization of single-crystal Gd(117)Co(56)Sn(112), a complex material with a primitive unit cell volume of ~6858 Å(3) and ~285 atoms per primitive unit cell (1140 atoms per face-centered cubic unit cell). The room temperature lattice thermal conductivity of this material is κ(L) = 0.28 W/(m·K) and represents one of the lowest ever reported for a nonglassy or nonionically conducting bulk solid. Furthermore, this material exhibits low resistivity at room temperature, and thus represents a true physical system that approaches the ideal phonon glass-electron crystal.
Publication Source (Journal or Book title)
Journal of the American Chemical Society
First Page
5965
Last Page
73
Recommended Citation
Schmitt, D. C., Haldolaarachchige, N., Xiong, Y., Young, D. P., Jin, R., & Chan, J. Y. (2012). Probing the lower limit of lattice thermal conductivity in an ordered extended solid: Gd117Co56Sn112, a phonon glass-electron crystal system. Journal of the American Chemical Society, 134 (13), 5965-73. https://doi.org/10.1021/ja300240g