Title

Density functional calculation of the structure and electronic properties of Cu(n)O(n) (n = 1-8) clusters

Document Type

Article

Publication Date

3-24-2011

Abstract

Ab initio simulations and calculations were used to study the structures and stabilities of copper oxide clusters, Cu(n)O(n) (n = 1-8). The lowest energy structures of neutral and charged copper oxide clusters were determined using primarily the B3LYP/LANL2DZ model chemistry. For n ≥ 4, the clusters are nonplanar. Selected electronic properties including atomization energies, ionization energies, electron affinities, and Bader charges were calculated and examined as a function of n.

Publication Source (Journal or Book title)

The journal of physical chemistry. A

First Page

2087

Last Page

95

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