Title

CrGaSe: A Quasi-Two-Dimensional Magnetic Semiconductor

Document Type

Article

Publication Date

11-19-2018

Abstract

We present a novel magnetic semiconductor, CrGaSe, synthesized by partially replacing magnetic Cr in antiferromagnetic CrSe with nonmagnetic Ga. The crystal structure of CrGaSe was determined by both powder and single-crystal X-ray diffraction. The title compound crystallizes in a monoclinic structure with space group C2/ m (No. 12). In CrGaSe, the Cr atoms are surrounded by 6 Se atoms and form filled octahedral clusters, while Ga atoms are centered in the Se tetrahedral clusters. The two kinds of clusters pack alternatingly along the c-axis, which results in a quasi-two-dimensional layered structure. The magnetization ( M) measurement shows the development of short-range ferromagnetic coupling below the Curie-Weiss (CW) temperature θ ∼ 92 K, evidenced by the nonlinear field dependence of M. However, the magnetic susceptibility exhibits a peak at low fields at ∼18 K, indicating the existence of an antiferromagnetic interaction as well. Electronic structure calculations using the WIEN2k program in the local spin density approximation indicate that the magnetism arises exclusively from local moments of the Cr atoms. The electrical resistivity measurement of the CrGaSe sample confirms that this material is a semiconductor with the band gap ∼0.26 eV. Meanwhile, the experimental band gap (∼0.26 eV) is close to the theoretical prediction using the WIEN2k program (∼0.35 eV).

Publication Source (Journal or Book title)

Inorganic chemistry

First Page

14298

Last Page

14303

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