Title
Amplifying fluorescent conjugated polymer sensor for singlet oxygen detection
Document Type
Article
Publication Date
8-7-2019
Abstract
A "higher energy gap" concept was applied towards designing an efficient turn-on amplifying sensor for singlet oxygen - an important biomedical and environmental monitoring analytical target. The concept is based on modulation of intramolecular energy transfer in fluorescent conjugated polymers through the formation of a higher energy gap "roadblock" upon reaction with a target analyte. The polymer sensor incorporates 1,4-disubstituted tetracene units which act as reactive sites for singlet oxygen. The resulting polymer sensor demonstrates significant fluorescent signal amplification and a broader analyte detection range relative to a corresponding small-molecule sensor.
Publication Source (Journal or Book title)
Chemical communications (Cambridge, England)
First Page
8955
Last Page
8958
Recommended Citation
Wang, C., & Nesterov, E. E. (2019). Amplifying fluorescent conjugated polymer sensor for singlet oxygen detection. Chemical communications (Cambridge, England), 55 (61), 8955-8958. https://doi.org/10.1039/c9cc04123k