Benzoporphyrins via an olefin ring-closure metathesis methodology

Lijuan Jiao, Louisiana State University
Erhong Hao, Louisiana State University
Frank R. Fronczek, Louisiana State University
M. Graça H. Vicente, Louisiana State University
Kevin M. Smith, Louisiana State University

Abstract

A new route to benzoporphyrins is reported in which readily available vicinal dibromoporphyrins are bis-allylated using the Suzuki reaction, cyclized by way of olefin metathesis and finally oxidized to give mono-, di-, or tri-benzoporphyrins. © The Royal Society of Chemistry 2006.