Document Type
Article
Publication Date
4-7-2017
Abstract
© 2017 American Chemical Society. We report the synthesis and investigation of an unprecedented 8-heteroaryl-fused BODIPY 4. This compound exhibits enhanced π-π stacking in the solid state, unusually large blue-shifts in the absorbance and emission spectra, and higher fluorescence quantum yield than its unfused precursor; DFT calculations suggest a small energy gap for 4 and strong electronic communication between the 8-OPh and the BODIPY core.
Publication Source (Journal or Book title)
Journal of Organic Chemistry
First Page
3880
Last Page
3885
Recommended Citation
Zhao, N., Xuan, S., Fronczek, F., Smith, K., & Vicente, M. (2017). Enhanced Hypsochromic Shifts, Quantum Yield, and π-π Interactions in a meso,β-Heteroaryl-Fused BODIPY. Journal of Organic Chemistry, 82 (7), 3880-3885. https://doi.org/10.1021/acs.joc.6b02981
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