Title
Mechanisms of aggregation in metalloporphyrins: Demonstration of a mechanistic dichotomy
Document Type
Article
Publication Date
12-1-1976
Abstract
N.m.r. spectroscopy is used to demonstrate that the predominant interaction in aggregations of magnesium(II) porphyrins [e.g. (1)] involves the metal atom in one molecule and the propionate carbonyl group in another; in contradistinction, the similarly strong aggregation observed for the first time in zinc(II) porphyrins [e.g. (2)] is shown to be independent of a metal to side-chain interaction.
Publication Source (Journal or Book title)
Journal of the Chemical Society, Chemical Communications
First Page
698
Last Page
699
Recommended Citation
Abraham, R., Eivazi, F., Pearson, H., & Smith, K. (1976). Mechanisms of aggregation in metalloporphyrins: Demonstration of a mechanistic dichotomy. Journal of the Chemical Society, Chemical Communications (17), 698-699. https://doi.org/10.1039/C39760000698