Title
Synthesis and characterization of halogeno- and pseudo-halogeno-thallium(III) porphyrin complexes. Variation of the co-ordination geometry as a function of the axial ligand
Document Type
Article
Publication Date
12-1-1993
Abstract
Several thallium(III) porphyrin complexes [Tl(por)X] with the axial ligand X = MeCO2, CF3CO2, Cl, Br, I, CN, SCN or N3, have been obtained via ligand-exchange reactions from the corresponding thallium(III) trifluoroacetates. All compounds were characterized by 1H NMR, UV/VIS spectroscopy, and elemental analysis. Fourteen compounds were investigated in detail by X-ray crystallography to obtain information on the influence of the axial ligand on the macrocycle core conformation in main-group metalloporphyrins and to establish the molecular stereochemistry of thallium(III) porphyrins with cyano, acetato, thiocyanato, bromo, iodo and azido groups as axial ligands.
Publication Source (Journal or Book title)
Journal of the Chemical Society, Dalton Transactions
First Page
3519
Last Page
3538
Recommended Citation
Senge, M., Ruhlandt-Senge, K., Regli, K., & Smith, K. (1993). Synthesis and characterization of halogeno- and pseudo-halogeno-thallium(III) porphyrin complexes. Variation of the co-ordination geometry as a function of the axial ligand. Journal of the Chemical Society, Dalton Transactions (23), 3519-3538. https://doi.org/10.1039/DT9930003519