"First syntheses of fused pyrroloporphyrins" by Laurent Jaquinod, Claude Gros et al.

Faculty Publications

Title

First syntheses of fused pyrroloporphyrins

Authors

Laurent Jaquinod, University of California, Davis
Claude Gros, University of California, Davis
Marilyn M. Olmstead, University of California, Davis
Michael Antolovich, University of California, Davis
Kevin M. Smith, University of California, Davis

Document Type

Article

Publication Date

1-1-1996

Abstract

(2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with α-isocyanoacetic esters in the presence of DBU to give the first β-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an α-isocyanoacetic ester.

Publication Source (Journal or Book title)

Chemical Communications

First Page

1475

Last Page

1476

Recommended Citation

Jaquinod, L., Gros, C., Olmstead, M., Antolovich, M., & Smith, K. (1996). First syntheses of fused pyrroloporphyrins. Chemical Communications (12), 1475-1476. https://doi.org/10.1039/cc9960001475

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