Title
Synthesis and electrochemistry of undeca-substituted metallo- benzoylbiliverdins
Document Type
Article
Publication Date
2-20-2006
Abstract
The high-yield preparation of metallo-benzoylbiliverdins 9, 10, and 11 from either oxidation of dodeca-substituted porphyrin 6 in the presence of NaNO 2/TFA and air followed by metalation or by reaction of the Ni(II) or Cu(II) complexes of 6 with m-chloroperoxybenzoic acid in pyridine under air is reported. The X-ray structures of complexes 9 and 10 and the electrochemistry and spectroelectrochemistry of metallo-benzoylbiliverdins 9-11 are presented and discussed. © 2006 American Chemical Society.
Publication Source (Journal or Book title)
Inorganic Chemistry
First Page
1463
Last Page
1470
Recommended Citation
Ongayi, O., Vicente, M., Ou, Z., Kadish, K., Kumar, M., Fronczek, F., & Smith, K. (2006). Synthesis and electrochemistry of undeca-substituted metallo- benzoylbiliverdins. Inorganic Chemistry, 45 (4), 1463-1470. https://doi.org/10.1021/ic050841c