Title
Size evolution of gold nanoparticles in a millifluidic reactor
Document Type
Article
Publication Date
1-16-2012
Abstract
The size evolution of gold nanoparticles in a millifluidic reactor is investigated using spatially resolved transmission electron microscopy (TEM). The experimental data is supported by numerical simulations, carried out to study the residence-time distribution (RTD) of tracers that have the same properties as Au ions. Size and size distribution of the particles within the channels are influenced by the mixing zones as well as the RTD. However, the Au nanoparticles obtained show a broader size distribution even at the shortest investigated residence time of 3.53 s, indicating that in addition to surface growth reaction kinetics also plays an important role. The comparison of time resolved particle growth within the millifluidic channel with flask-based reactions reveals that the particle size can be controlled better within millifluidic channels. Overall, the results indicate potential opportunities to utilize easy to fabricate millifluidic reactors for the synthesis of nanoparticles, as well as as for carrying out time resolved kinetic studies.
Publication Source (Journal or Book title)
Chemphyschem : a European journal of chemical physics and physical chemistry
First Page
177
Last Page
82
Recommended Citation
Li, Y., Sanampudi, A., Raji Reddy, V., Biswas, S., Nandakumar, K., Yemane, D., Goettert, J., & Kumar, C. S. (2012). Size evolution of gold nanoparticles in a millifluidic reactor. Chemphyschem : a European journal of chemical physics and physical chemistry, 13 (1), 177-82. https://doi.org/10.1002/cphc.201100726