Using cellulose nanocrystals as a sustainable additive to enhance hydrophilicity, mechanical and thermal properties of poly(vinylidene fluoride)/poly(methyl methacrylate) blend

Document Type

Article

Publication Date

4-6-2015

Abstract

The aim of this study is to use cellulose nanocrystals (CNCs) as a sustainable additive for improving hydrophilicity, mechanical and thermal properties of poly(vinylidene fluoride) (PVDF)/poly(methyl methacrylate) (PMMA) blends. A casting-evaporation method was used to prepare the nanocomposites, and their surface wettability, mechanical, thermal and morphological properties were characterized. With the addition of only 3 wt% CNCs, tensile strength, tensile modulus, dynamic storage modulus at 45 °C, and onset thermal decomposition temperature of the ternary composite exhibited 32%, 70%, 36% and 4.0 °C increase, respectively, while the static water angle decreased by 6°. As the CNC content increased to 6 wt %, further improvement was observed in all above properties except tensile strength. The observed performance enhancement is attributed to a considerably increased crystallinity of PVDF (e.g., from 28.5% for the binary blend to 43.3% for ternary composite at the 3 wt % CNC level). Our present work demonstrates the importance of using sustainable CNCs to achieve synergetic improvement in physical and mechanical performance of PVDF/PMMA blend, suggesting a facile way to prepare nanocomposites for potential membrane-based separation applications.

Publication Source (Journal or Book title)

ACS Sustainable Chemistry and Engineering

First Page

574

Last Page

582

This document is currently not available here.

Share

COinS