Two metal-organic frameworks (MOFs) assembled from one asymmetric semirigid multicarboxylate ligand: Syntheses and crystal structural characterizations

Document Type

Article

Publication Date

1-15-2012

Abstract

Hydrothermal reactions between a new flexible multicarboxylate ligand of 3-(2-carboxy-phenoxy)-benzoic acid (H 2L) and transitional metal cations of M 2+ (M = Cu 2+, Ni 2+) in the presence of the secondary ligands of 1,10-phenanthroline (phen), 2,2'-bipyridine (2,2'-bpy), and 4,4'-bipyridine (4,4'-bpy) afford two novel coordination polymers Ni 2(H 2O) 2L 2(phen)(μ-4, 4'-bpy).

Publication Source (Journal or Book title)

Jiegou Huaxue

First Page

61

Last Page

66

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