A H-bond Induced Zinc 2D Coordination Polymer Linked by 1, 3-Benzenebicarboxylate
Document Type
Article
Publication Date
12-1-2001
Abstract
A H-bond induced two-dimensional infinite coordination polymer [Zn(1, 3-BDC) (Im) 2] n · 2nCH3OH(1, 3-BDC = l, 3-benzenedicarboxylate, Im = imidazole) was synthesized and crystallographically determined by X-ray diffraction. The crystal structure belongs to monoclinic system with space group C2/ c. a = 23. 1836(2), 6 = 10.1905(1), c = 17. 0118(2) Å, β = 115.099°, V = 3639.58(6) Å3, D = 1. 499g · cm-3, Z = 8, F000 = 1688, μ= 1.384mm-1, R1,= 0.0715, w R2 = 0. 1645. Each Zn (II) ion is four-coordinated with a geometry of distorted tetrahedron. Each 1, 3-BDC acts as a bridge to bond two neighboring zinc ions, leading to an infinite one-dimensional chainlike coordination polymer. Each chain was linked by hydrogen bonds with its neighbors to form a two-dimensional net.
Publication Source (Journal or Book title)
Chinese Journal of Inorganic Chemistry
Recommended Citation
Li, B., Sun, Y., Gou, S., Yao, J., Chantrapromma, S., & Fun, H. (2001). A H-bond Induced Zinc 2D Coordination Polymer Linked by 1, 3-Benzenebicarboxylate. Chinese Journal of Inorganic Chemistry, 17 (6) Retrieved from https://repository.lsu.edu/ag_exst_pubs/1059