One-pot synthesis of in-situ carbon-coated Fe3O4 as a long-life lithium-ion battery anode

Document Type

Article

Publication Date

3-16-2017

Abstract

Fe3O4 has been regarded as a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity, low cost, and environmental friendliness. In this work, we present a one-pot reducing-composite-hydroxide-mediated (R-CHM) method to synthesize in situ carbon-coated Fe3O4 (Fe3O4@C) at 280 °C using Fe(NO3)3 • 9H2O and PEG800 as raw materials and NaOH/KOH as the medium. The as-prepared Fe3O4 octahedron has an average size of 100 nm in diameter, covered by a carbon layer with a thickness of 3 nm, as revealed by FESEM and HRTEM images. When used as anode materials in LIBs, Fe3O4@C exhibited an outstanding rate capability (1006, 918, 825, 737, 622, 455 and 317 mAh g-1 at 0.1, 0.2, 0.5, 0.8, 1.0, 1.5 and 2.0 A g-1). Moreover, it presented an excellent cycling stability, with a retained capacity of 261 mAh g-1 after 800 cycles under an extremely high specific current density of 2.0 A g-1. Such results indicate that Fe3O4@C can provide a new route into the development of long-life electrodes for future rechargeable LIBs. Importantly, the R-CHM developed in our work can be extended for the synthesis of other carbon-coated electrodes for LIBs and functional nanostructures for broader applications.

Publication Source (Journal or Book title)

Nanotechnology

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