Nickel monosilicide contact formation in electrolessly etched silicon nanowires deposited onto nickel electrodes

Document Type

Article

Publication Date

6-1-2009

Abstract

Large arrays of silicon nanowires are fabricated by electroless etching of (100) p-type silicon wafers: The nanowires are separated from substrates, deposited onto interdigitated nickel electrodes, and annealed to form silicide contacts. Two-probe electrical characterization of interdigitated electrodes with hundreds of silicided nanowires deposited across electrode pairs shows a linear current-voltage behavior with an estimated nanowire resistivity approximately equal to the parent wafer. Results from X-ray photoelectron spectroscopy and X-ray absorption near-edge structure show the formation of a nickel monosilicide (NiSi) phase near the tips of nanowires adjacent to nickel reservoirs during an anneal. The work shows that a facile and nonvacuum process may be used to create ohmic contacts between high volumes of nanowires and pre-existing electrodes. © 2009 The Electrochemical Society.

Publication Source (Journal or Book title)

Journal of the Electrochemical Society

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