Document Type
Article
Publication Date
4-30-2021
Abstract
Secondary lithium-bromine (Li–Br2) batteries offer cell potentials near 4 V and storage capacities over 1200 Whkg−1-LiBr. Here, we demonstrate Li–Br2 cells with two types of carbonized metal-organic frameworks (MOFs). Carbonized MIL-53(Al) electrodes show capacities of 224 mAhg−1 LiBr (at 3.4 V) and 72% capacity retention after 100 cycles, while carbonized ZIF-8 electrodes show specific capacities of 273 mAhg−1 LiBr and 88% capacity retention over 100 cycles at 1C (at 3.4 V). Surface characterization (XPS, EDS) and porosimetry indicate that the ZIF-8 derived MOF electrodes are heavily microporous with heteroatom (C–N) doping. The increased capacity and reversibility of ZIF-8 derived carbon during cyclic voltammetry and cycling measurements is ascribed to higher LiBr loadings, enhanced bromine trapping and adsorption due to the electrode microporosity and heteroatom bonding.
Publication Source (Journal or Book title)
Journal of Power Sources
Recommended Citation
Peterson, B., Andrews, E., Hung, F., & Flake, J. (2021). Carbonized metal-organic framework cathodes for secondary lithium-bromine batteries. Journal of Power Sources, 492 https://doi.org/10.1016/j.jpowsour.2021.229658