Document Type
Article
Publication Date
12-19-2016
Abstract
The present work describes the development of high performance cellulose nanocrystals/carboxymethyl cellulose (CNC/CMC) films through a rational design of CNC surface chemistry. Considering the anionic surface nature of CMC, surface cationization of CNCs was performed in order to build strong interfacial bonding by electrostatic attraction and form uniform dispersion state by electrostatic repulsion. Nanocomposite films were fabricated by dispersing the CNCs and cationically modified CNCs (mCNCs) in CMC matrix through solution casting. The resultant CNC/CMC and mCNC/CMC films were then evaluated in terms of processability, mechanical properties and fracture surface morphology. Results showed that the reinforcing capacity of mCNCs was greatly dependent on its substitution degree. High substitution degree was favorable for obtaining mCNC/CMC film with uniform dispersion and superior mechanical properties. The observed distinctive reinforcing phenomena from CNCs and mCNCs in CMC matrix were interpreted in terms of dispersion state and interfacial bonding based on the fracture surface morphology.
Publication Source (Journal or Book title)
Polymer
First Page
200
Last Page
210
Recommended Citation
Li, M., Mei, C., Xu, X., Lee, S., & Wu, Q. (2016). Cationic surface modification of cellulose nanocrystals: Toward tailoring dispersion and interface in carboxymethyl cellulose films. Polymer, 107, 200-210. https://doi.org/10.1016/j.polymer.2016.11.022